Papers

No.133Mechanism of the Asymmetric Dehydrative Allylative Cyclization of Alcohols to Cyclic Ethers Catalyzed by a CpRu Complex of the Chiral Picolinic Acid-Type Ligand, Cl-Naph-PyCOOH: Is a π-Allyl Intermediate Present?

Suzuki, Y.; Iwase, S.; Ratanasak, M.; Hasegawa, J.; Tanaka, S.; Kitamura, M. Bull. Chem. Soc. Jpn. 2021, 94, 440–450. (Selected  Paper)

No.132A Monocationic Zn(II) Acetate Complex of a Chiral Bisamidine Dioxolane Ligand, Naph-diPIM-dioxo-R, for the Asymmetric 1,3-Dipolar Cycloaddition of Tridentate α-Substituted α-Imino Esters and Acrylates to Multi-Substituted Prolines: Importance of an n-π* Interaction for High Enantioselectivity

Kiran, I. N. C.; Fujita, K.; Kobayashi, K.; Tanaka, S.; Kitamura, M. Bull. Chem. Soc. Jon. 2021, 94, 295–308. (Selected Paper)

No.131Asymmetric Synthesis of Multi‐substituted Prolines via a Catalytic 1,3‐Dipolar Cycloaddition Using a Monocationic ZnIIOAc Complex of a Chiral Bisamidine Ligand, Naph‐diPIM‐dioxo‐R

Kiran, I. N. C.; Fujita, K.; Tanaka, S.; Kitamura, M. ChemCatChem 2020, 12, 5613–5617.

No.130Mechanism Change of (+)-Nonlinear Effect in a Phase Separation System in a CuII-Catalyzed Asymmetric Friedel-Crafts Reaction Using a C2-Chiral Dioxolane-Containing-Bisamidine Ligand, Naph-diPIM-dioxo-iPr

Le, T. P.; Tanaka, S.; Yoshimura, M.; Kitamura, M. Bull. Chem. Soc. Jpn. 2020, 93, 1319–1333.

No.129CpRu/Brønsted Acid-Catalyzed Enantioselective Dehydrative Cyclization of Pyrroles N-Tethered with Allylic Alcohols

Iwase, S.; Suzuki, Y.; Tanaka, S.; Kitamura, M. Org. Lett. 2020, 22, 1929–1933.

No.128CpRuII-chiral bisamidine complex catalyzed asymmetric Carroll-type decarboxylative allylation of β-keto allyl esters

Ogawa, S.; Miyata, K.; Kawakami, S.; Tanaka, S.; Kitamura, M. Tetrahedron 2020, 76, 130888.

No.127Rapid Entry into Biologically Relevant α,α-Difluoroalkylphosphonates Bearing Allyl Protection−Deblocking under Ru(II)/(IV)-Catalysis

Panigrahi, K.; Fei, X.; Kitamura, M.; Berkowitz, D. B. Org. Lett. 2019, 21, 9846–9851.

No.126Short and Atom-Economic Enantioselective Synthesis of the σ1‐Receptor Ligands (S)- and (R)‐Fluspidine—Important Tools for Positron Emission Tomography Studies

Bunse, P.; Schlepphorst, C.; Glorios, F.; Kitamura, M.; Wünsch, B. J. Org. Chem. 2019, 84, 13744–13754.

No.125Synthesis of the core structure of phalarine

Douki, K.; Shimokawa, J.; Kitamura, M. Org. Biomol. Chem. 2019, 17, 1727–1730.

No.124Water, an Essential Element for a ZnII‐Catalyzed Asymmetric Quinone Diels‐Alder Reaction: Multi‐Selective Construction of Highly Functionalized cis‐Decalins

Morimoto, K.; Le, T. P.; Manna, S. K.; Kiran, I. N. C.; Tanaka, S.; Kitamura, M. Chem. Asian J. 2019, 14, 3283–3290.

No.123A Chiral Picolinic Acid Ligand, Cl-Naph-PyCOOH, for CpRu-Catalyzed Dehydrative Allylation: Design, Synthesis, and Properties

Tanaka, S.; Suzuki, Y.; Kimura, T.; Kitamura, M. Bull. Chem. Soc. Jpn 2019, 92, 1707–1720.

No.122Bisamidine–Cu(I)-catalyzed C-Allylation of 1,3-Dicarbonyl Compounds with Simple Cyclic Alkenes Using Di-tert-butyl Peroxide

Tanaka, S.; Ramachandran, G.; Hori, Y.; Kitamura, M. Chem. Lett. 2018, 47, 1486–1489.

No.121Revisiting the CuII-Catalyzed Asymmetric Friedel–Crafts Reaction of Indole with Trifluoropyruvate

Le, T. P.; Higashita, K.; Tanaka, S.; Yoshimura, M.; Kitamura, M. Org. Lett. 2018, 20, 7149–7153.

No.120Mechanistic Study of the Ru-Catalyzed Asymmetric Hydrogenation of Nonchelatable and Chelatable tert-Alkyl Ketones Using the Linear Tridentate sp3P/sp3NH/sp2N-Combined Ligand PN(H)N: RuNH- and RuNK-Involved Dual Catalytic Cycle

Nakane, S.; Yamamura, T.; Manna, S. K.; Tanaka, S.; Kitamura, M. ACS Catal. 2018, 8, 11059–11075.

No.119Synthesis of fluspidine via asymmetric NaBH4 reduction of silicon enolates of b-keto esters

Nakane, S.; Yoshinaka, S.; Iwase, S.; Shuto, Y.; Bunse, P.; Wünsch, B.; Tanaka, S.; Kitamura, M. Tetrahedron 2018, 74, 5069–5084.

No.118Synthetic Study toward Total Synthesis of (±)-Germine: Synthesis of (±)-4-Methylenegermine

Stork, G.; Yamashita, A.; Hanson, R. M.; Phan, L.; Phillips, E.; Dubé, D.; Bos, P. H.; Clark, A. J.; Gough, M.; Grrenlee, M. L.; Jiang, Y.; Jones, K.; Kitamura, M.; Leonard, J.; Liu, T.; Parsons, P. J.; Venkatesan, A. M. Org. Lett. 2017, 19, 5150–5153.

No.117Modular Construction of Protected 1,2/1,3-Diols, -Amino Alcohols, and -Diamines via Catalytic Asymmetric Dehydrative Allylation: An Application to Synthesis of Sphingosine

Tanaka, S.; Gunasekar, R.; Tanaka, T.; Iyoda, Y.; Suzuki, Y.; Kitamura, M. J. Org. Chem. 2017, 82, 9160–9170.

No.116Synthetic analogs of a protozoan glycolipid designed to combat intracellular Leishmania infection
No.115π-Allyl Donicity Switch in Catalytic Asymmetric Allylation: Usability of a Robust and Feasible Allyl Methyl Ether

Suzuki, Y.; Iwase, S.; Hashimoto, K.; Tanaka, S.; Kitamura, M. Chem. Lett. 2017, 46, 1308–1310.

(Editor’s Choice)

No.114Synthesis and biological evaluation of chemokine receptor ligands with 2-benzazepine scaffold

Thum, S.; Kokornaczyk, A. K.; Seki, T.; Maria, M. D.; Zacarias, N. V. O.; Vries, H.; Weiss, C.; Koch, M.; Schepmann, D.; Kitamura, M.; Tschammer, N.; Heitman, L. H.; Junker, A.; Wünsch, B. Eur. J. Med. Chem. 2017, 135, 401–413.

No.113Do GluN2B subunit containing NMDA receptors tolerate a fluorine atom in the phenylalkyl side chain?

Shuto, Y.; Thum, S.; Temme, L.; Schepmann, D.; Kitamura, M.; Wünsch, B. Med. Chem. Commun. 2017, 8, 975–981.

No.112Enantio- and Diastereoselective Dehydrative “One-Step” Construction of Spirocarbocycles via a Ru/H+-Catalyzed Tsuji-Trost Approach

Suzuki, Y.; Vatmurge, N.; Tanaka, S.; Kitamura, M. Chem. Asian J. 2017, 12, 633–637.

No.111Enantioselective Total Synthesis of (+)-Hinckdentine A via a Catalytic Dearomatization Approach

Douki, K.; Ono, H.; Taniguchi, T.; Shimokawa, J.; Kitamura, M.; Fukuyama, T. J. Am. Chem. Soc. 2016138, 14578–14581.
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No.110Development of a Divergent Synthetic Route to the Erythrina Alkaloids: Asymmetric Syntheses of 8-Oxo-erythrinine, Crystamidine, 8-Oxo-erythraline, and Erythraline

Umihara, H.; Yoshiko, T.; Shimokawa, J.; Kitamura, M.; Fukuyama, T. Angew. Chem. Int. Ed. 201655, 6915–6918

No.109Development of an axially chiral sp³P/sp³NH/sp²N-combined linear tridentate ligand—fac-Selective formation of Ru(II) complexes and application to ketone hydrogenation

Yamamura, T.; Nakane, S.; Nomura, Y.; Tanaka, S.; Kitamura, M. Tetrahedron 201672, 3781–3789.

No.108Stereochemical Stability Differences between Axially Chiral 6-Aryl-substituted Picolinic Esters and Their Benzoic Ester Derivatives: sp2N: vs sp2CH in CH3, C6H5, and CH3O ortho-Substitution Effect

Tanaka, S.; Suzuki, Y.; Matsushita, M.; Kitamura, M. Bull. Chem. Soc. Jpn. 201588, 1726–1734.20150262figc

No.107Intramolecular Tsuji–Trost-type Allylation of Carboxylic Acids: Asymmetric Synthesis of Highly π-Allyl Donative Lactones

Suzuki, Y.; Seki, T.; Tanaka, S.; Kitamura, M. J. Am. Chem. Soc2015137, 9539–9542.

ja-2015-05786g_0007

No.106Catalytic Dehydrogenative N-((Triisopropylsilyl)oxy)carbonyl (Tsoc) Protection of Amines Using iPr3SiH and CO2

Tanaka, S.; Yamamura, T.; Nakane, S.; Kitamura, M. Chem. Commun201551, 13110–13112.%e3%82%b9%e3%82%af%e3%83%aa%e3%83%bc%e3%83%b3%e3%82%b7%e3%83%a7%e3%83%83%e3%83%88-2016-09-23-11-24-38

No.105Soft Ruthenium and Hard Brønsted Acid Combined Catalyst for Efficient Cleavage of Allyloxy Bonds. Application to Protecting Group Chemistry

Tanaka, S.; Suzuki, Y.; Saburi, H.; Kitamura, M. Tetrahedron 201571, 6559–6568.

No.104Donor-Acceptor Bifunctional Molecular Catalyst: Its Development, Application, and Analysis

Kitamura, M.; Tanaka, S.; Yoshimura, M. J. Synth. Org. Chem., Jpn. 201573, 690–700.

No.103Mechanism of Asymmetric Hydrogenation of Aromatic Ketones Catalyzed by a Combined System of Ru(π-CH2C(CH3)CH2)2(cod) and the Chiral sp2N/sp3NH Hybrid Linear N4 Ligand Ph-BINAN-H-Py

Nakatsuka, H.; Yamamura, T.; Shuto, Y.; Tanaka, S.; Yoshimura, M.; Kitamura, M. J. Am. Chem. Soc. 2015, 137, 8138–8149.

 

ja-2015-02350u_0019

No.102Asymmetric NaBH4 1,4-Reduction of C3-Disubstituted 2-Propenoates Catalyzed by a Diamidine Cobalt Complex

Shuto, Y.; Yamamura, T.; Tanaka, S.; Yoshimura, M.; Kitamura, M.; ChemCatChem 2015, 7, 1547-1550.

No.101Recent topics in catalytic asymmetric hydrogenation of ketones

Yoshimura, M.; Tanaka, S.; Kitamura, M.; Tetrahedron Lett. 2014, 55, 3635-3640.

No.100Asymmetric Hydrogenation of tert-Alkyl Ketones: DMSO Effect in Unification of Stereoisomeric Ruthenium Complexes

Yamamura, T.; Nakatsuka, H.; Tanaka, S. Kitamura, M.; Angew. Chem. Int. Ed. 2013, 52, 9313-9315.

Featured in Synfacts: Synfacts 2013, 9, 1190.

No.99CpRu-catalyzed asymmetric dehydrative allylation

Kitamura, M.; Miyata, K.; Seki, T.; Vatmurge, N.; Tanaka, S. Pure. Appl. Chem. 2013, 56, 1121-1132.

No.98Reaction of Frustrated Lewis Pairs with Ketones and Esters.

Xu, B-H.; Yanez, R. A. A.; Nakatsuka, H.; Kitamura, M.; Fröhlich, R.; Kehr, G.; Erker, G. Chem. Asian J. 2012, 7, 1347–1356.

No.97Double Arylation of Acetylenedicarboxylate with B(C6F5)3.

Nakatsuka, H.; Fröhlich, R.; Kitamura, M.; Kehr, G.; Erker, G. Eur. J. Inorg. Chem. 2012, 1163-1166.

No.96Asymmetric Dehydrative C-, N-, and O-Allylation Using Naph-diPIM-dioxo-i-Pr-CpRu/p-TsOH Combined Catalyst.

Miyata, K.; Kitamura, M. Synthesis 2012, 44.

No.95Enantioselective Synthesis of Pyrrolidine-, Piperidine-, and Azepane-Type N-Heterocycles with α-Alkenyl Substitution: The CpRu-Catalyzed Dehydrative Intramolecular N-Allylation Approach.

Seki, T.; Tanaka, S.; Kitamura, M. Org. Lett. 2012, 14, 608-611.

ol-2011-03218d_0001

No.94Desymmetric hydrogenation of a meso-cyclic acid anhydride toward biotin synthesis.

Yoshimura, M.; Tsuda, K.; Nakatsuka, H.; Yamamura, T.; Kitamura, M. Tetrahedron 2011, 67, 10006-10010.

1-s2.0-S0040402011014220-fx1

No.93A Chiral Bidentate sp2-N Ligand, Naph-diPIM: Application to CpRu-Catalyzed Asymmetric Dehydrative C-, N-, and O-Allylation.

Miyata, K.; Kutsuna, H.; Kawakami, S.; Kitamura, M. Angew. Chem. Int. Ed. 2011, 50, 4649-4653.

No.92Catalytic Dehydrative S-Allylation of Cysteine-Containing Peptides in Aqueous Media toward Lipopeptide Chemistry.

Jaisankar, P.; Tanaka, S.; Kitamura, M. J. Org. Chem. 2011, 76, 1894-1897.2011.

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No.91Mechanistic Insight into NOYORI Asymmetric Hydrogenations.

Kitamura, M.; Nakatsuka, H. Chem. Commun. 2011, 47, 842-846.

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No.90Ruthenium(1+), (5-2,4-Cyclopentadien-1-yl)(3-2-propen-1-yl)(2-quinolinecarboxylato-N1,O2)-, Hexafluorophosphate(1-) (1:1).

S. Tanaka and M. Kitamura , Ruthenium(1+),  e-EROS Encyclopedia of Reagents for Organic Synthesis, 2010, John Wiley & Sons, Ltd, On-line.

No.89(9H-Fluoren-9-yl)methanesulfonyl (Fms): An Amino Protecting Group Complementary to Fmoc.

Ishibashi, Y.; Miyata, K.; Kitamura, M. Eur. J. Org. Chem. 2010, 4201-4204.

No.88Synthesis of 3,3′-Diaryl-substituted 2,2′-diamino-1,1′-binaphthyl (diAr-BINAN) and Its Derivatives.

Yoshimura, M.; Muraoka, T.; Nakatsuka, H.; Huang, H.; Kitamura, M. J. Org. Chem. 2010, 75, 4315-4318.

jo-2010-00638j_0001

No.87Highly Efficient Catalytic Dehydrative S-Allylation of Thiols and Thioic S-Acids.

Tanaka, S.; Pradhan, P. K.; Maegawa, Y.; Kitamura, M. Chem. Commun. 2010, 46, 3996-3998.

GA2

No.86Asymmetric Dehydrative Cyclization of ω-Hydroxy Allyl Alcohols Catalyzed by Ruthenium Complexes.

Tanaka, S.; Seki, T.; Kitamura, M. Angew. Chem. Int. Ed. 2009, 48, 8948-8951.

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No.85Solid-phase Synthesis of Protected α-Amino Phosphonic Acid Oligomers.

Y. Ishibashi and M. Kitamura, Chem. Commun. 2009, 6985-6987.

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No.84A Magnetically Separable Heterogeneous Deallylation Catalyst: [CpRu(η3-C3H5)(2-pyridinecarboxylato)]PF6 Complex Supported on a Ferromagnetic Microsize Particle Fe3O4@SiO2.

T. Hirakawa, S. Tanaka, N. Usuki, H. Kanzaki, M. Kishimoto, and M. Kitamura, Eur. J. Org. Chem., 6, 789-792 (2009).

No.83Dehydrative Allylation of Alcohols and Deallylation of Allyl Ethers Catalyzed by [CpRu(CH3CN)3]PF6 and 2-Pyridinecarboxylic Acid Derivatives. Effect of π-accepting ability and COOH acidity of Ligand on Reactivity.

S. Tanaka, H. Saburi, T. Hirakawa, T. Seki, and M. Kitamura, Chem. Lett., 38, 188-189 (2009).

No.82A new, efficient and direct preparation of TlTp and related complexes with TlBH4.

M. Kitamura, Y. Takenaka, T. Okuno, R. Holl, and B. W?nsch. Eur. J. Inorg. Chem., 2008, 1188-1192.

No.81Synthesis of 2,5-Diazabicyclo[2.2.2]octanes by Dieckmann Analogous Cyclization.

R. Holl, M. Dykstra, M. Schneiders, R. Froehlich, M. Kitamura, E. U. Wuerthwein, and B. Wünsch, Aust. J. Chem., 61, 914-919 (2008).

No.80Solvent-free One-pot Synthesis of Thallium Complexes of Tp [BH(Pz)3]- (Pz = pyrazolate) and Its Derivatives.

K. Tsuda, K. Miyata, T. Okuno, M. Yoshimura, S. Tanaka, and M. Kitamura, refereed, Tetrahedron Lett., 2008, 49, 2990-2993.

1-s2.0-S0040403908003973-fx1

No.79Enantiomeric Products Formed via Different Mechanisms: Asymmetric Hydrogenation of an α,β-Unsaturated Carboxylic acid Involving a Ru(CH3COO)2[(R)-binap] Catalyst.

M. Yoshimura, Y. Ishibashi, K. Miyata, Y. Bessho, M. Tsukamoto, and M. Kitamura, Tetrahedron, 63, 11399-11409 (2007).

No.78アルドール化合物の構造化学.

Kitamura, M.; Nakano, K. J. Synth. Org. Chem. Jpn., 65, 552-562 (2007).

No.77A New Synthetic Route to Oligoribonucleotides Based on CpRu-Catalyzed Deallylation.

S. Tanaka, T. Hirakawa, K. Ohishi, Y. Hayakawa, and M. Kitamura, Tetrahedron Lett., 48, 7320-7322 (2007).

No.76Highly Reactive and Chemoselective Cleavage of Allyl Esters Using an Air- and Moisture-Stable [CpRu(IV)(π-C3H5)(2-quinolinecarboxylato)]PF6 Catalyst.

S. Tanaka, H. Saburi, T. Murase, Y. Ishibashi, and M. Kitamura, J. Organomet. Chem., 692, 295-298 (2007).

No.75Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp2N/sp3N Hybrid Ligands R-BINAN-R’-Py.

H. Huang, T. Okuno, K. Tsuda, M. Yoshimura, and M. Kitamura,  J. Am. Chem. Soc., 128, 8716-8717 (2006).

No.74Mechanism of Catalytic Asymmetric Hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline Using Ru(CH3COO) 2[(S)-binap].

M. Tsukamoto, M. Yoshimura, K. Tsuda, and M. Kitamura, Tetrahedron, 62, 5448-5453 (2006).

No.73Catalytic Removal of N-Allyloxycarxbonyl Groups Using the [CpRu(IV)(p-C3H5)(2-quinolinecarboxylato)]PF6 Complex. A New Efficient Deprotecting Method in Peptide Synthesis.

S. Tanaka, H. Saburi, T. Murase, M. Yoshimura, and M. Kitamura, J. Org. Chem., 71, 4682-4684 (2006).

No.72[CpRu(IV)(π-C3H5)(2-quinolinecarboxylato)]PF6 Complex. A Robust Catalyst for the Cleavage and Formation of Allyl Ethers.

S. Tanaka, H. Saburi, and M. Kitamura, Adv. Synth. Catal., 348, 375-378 (2006).

No.71Ten Years of Research on NOBIN Chemistry,

K. Ding, X. Li, B. Ji, H. Guo, and M. Kitamura, Current Organic Synthesis, 2, 499-545 (2005)

※DOI不明

No.70Origin of the Minor Enantiomeric Product in a Noyori Asymmetric Hydrogenation: Evidence for Pathways Different to the Major Mechanism.

Y. Ishibashi, Y. Bessho, M. Yoshimura, M.Tsukamoto, and M. Kitamura, Angew. Chem. Int. Ed., 44, 7287-7290 (2005).

No.69Recent Advances of Mechanistic Studies on Asymmetric Hydrogenation of Dehydroamino Acid Derivatives Catalyzed by Diphosphine-Rh and -Ru Complexes.

M. Tsukamoto and M. Kitamura.  J. Synth. Org. Chem. Jpn., 63, 899-910 (2005).

No.68Catalytic Dehydrative Allylation of Alcohols.

H. Saburi, S. Tanaka, and M. Kitamura.  Angew. Chem. Int. Ed., 44, 1730-1732 (2005).

No.67Catalytic Enantioselective Addition of Dialkylzincs to Aldehydes Using (2S)-(-)-3-exo-(Dimethylamino)isoborneol [(2S)-DAIB]: (S)-1-Phenyl-1-Propanol.

M. Kitamura, H. Oka, S. Suga, K. Nakano, and R. Noyori, Org. Synth., 79, 139-145, Collective Volume X (2004).

No.66CpRuIIPF6/Quinaldic Acid-Catalyzed Chemoselective Allyl Ether Cleavage. A Simple and Practical Method for Hydroxyl Deprotection.

S. Tanaka, H. Saburi, Y. Ishibashi, and M. Kitamura, Org. Lett., 6, 1873-1875 (2004).

No.65Toward Efficient Asymmetric Hydrogenation: Architectural and Functional Engineering of Chiral Molecular Catalysts.

R. Noyori, M. Kitamura, and T. Ohkuma, Proc. Natl. Acad. Sci. USA., 101, 5356-5362 (2004).

No.641,4-Addition of Diethylzinc to Cyclohexenone Catalyzed by CuOTf-Sulfonamide Combined System. Evidence Supporting a Concerted Mechanism.

K. Nakano, Y. Bessho, and M. Kitamura. Chem. Lett., 32, 224-225 (2003).

No.63Cycloalkanone-Based Threo and Erythro Aldols as Supramolecular Synthons in Crystal Engineering.

M. Kitamura and K. Nakano.  Crystal Growth & Design, 3, 25-34 (2003).

No.62Pressure-dependent Enantioselectivity in the Organozinc Addition to Aldehydes in Supercritical Fluids.

P. G. Jessop, R. A. Brown, M. Yamakawa, J. Xiao, T. Ikariya, M. Kitamura, S. C. Tucker, and R. Noyori, J. Supercrit. Fluids, 24, 161-172 (2002).

No.61Catalytic Leuckart-Wallach-type Reductive Amination of Ketones.

M. Kitamura, D. Lee, S. Hayashi, S. Tanaka, and M. Yoshimura. J. Org. Chem., 67, 8685-8687 (2002).

No.60(P(C6H5)3)CpRu+-Catalyzed Deprotection of Allyl Carboxylic Esters.

M. Kitamura, S. Tanaka, and M. Yoshimura, J. Org. Chem., 67, 4975-4977 (2002).

No.59Mechanism of Asymmetric Hydrogenation of α-(Acylamino)acrylic Esters Catalyzed by BINAP-Ruthenium(II) Diacetate.

M. Kitamura, M. Tsukamoto, Y. Bessho, M. Yoshimura, U. Kobs, M. Widhalm, and R. Noyori, J. Am. Chem. Soc., 124, 6649-6667 (2002).

No.58Catalytic Enantioselective Addition of Dialkylzincs to Aldehydes Using (2S)-(-)-3-exo-(Dimethylamino)isoborneol [(2S)-DAIB]: (S)-1-Phenyl-1-Propanol.

M. Kitamura, H. Oka, S. Suga, and R. Noyori, Org. Synth., 79, 139-141 (2002).

No.57Stereochemistry of Aldols: Configuration and Conformation of Aldols Derived from Cycloalkanones and Aldehydes.

M. Kitamura, K. Nakano, T. Miki, M. Okada, and R. Noyori, J. Am. Chem. Soc., 123, 8939-8950 (2001).

No.56Self and Nonself Recognition of Chiral Catalysts: The Origin of Nonlinear Effects in the Amino-Alcohol Catalyzed Asymmetric Addition of Diorganozincs to Aldehydes.

R. Noyori, S. Suga, H. Oka and M. Kitamura, Chem. Rec., 1, 85-100 (2001).

No.55Palladium-Catalyzed Cross-Coupling of 3-Iodobut-3-enoic Acid with Organometallic Reagents. Synthesis of 3-Substituted But-3-enoic Acids.

M. Abarbri, J. Parrain, M. Kitamura, R. Noyori, and A. Duch?ne, J. Org. Chem., 65, 7475-7478 (2000).

No.541,4-Addition of Diorganozincs to α,β-Unsaturated Ketones Catalyzed by a Copper(I)-Sulfonamide Combined System.

M. Kitamura, T. Miki, K. Nakano and R. Noyori, Bull. Chem. Soc. Jpn., 73, 999-1014 (2000).

No.53Asymmetric Synthesis of β-Hydroxy Sulfonic Acids by BINAP/Ru-Catalyzed Hydrogenation.

M. Kitamura, M. Yoshimura, N. Kanda and R. Noyori, Tetrahedron, 55, 8769-8785 (1999).

No.52Asymmetric Addition of Dialkylzincs to Benzaldehyde Derivatives Catalyzed by Chiral β-Amino Alcohols. Evidence for the Monomeric Alkylzinc Aminoalkoxide as Catalyst.

M. Kitamura, H. Oka, and R. Noyori, Tetrahedron, 55, 3605-3614 (1999).

No.51Synthesis of α-Amino Phosphonic Acids by Asymmetric Hydrogenation.

M. Kitamura, M. Yoshimura, M. Tsukamoto and R. Noyori, Peptide-Science-Present and Future, 586-588 (1998).

※DOI判別つかず

No.50Quantitative Analysis of the Chiral Amplification in the Amino Alcohol-Promoted Asymmetric Alkylation of Aldehydes with Dialkylzincs.

M. Kitamura, S. Suga, H. Oka, and R. Noyori, J. Am. Chem. Soc., 120, 9800-9809 (1998).

No.49Synthesis of α-Amino Phosphonic Acids by Asymmetric Hydrogenation.

M. Kitamura, M. Yoshimura, M. Tsukamoto, and R. Noyori, Enantiomer, 1, 281-303 (1996).

No.48Conjugate Addition of Diorganozincs to α,β-Unsaturated Ketones Catalyzed by a Copper(I)-Sulfonamide Combined System.

M. Kitamura, T. Miki, K. Nakano, and R. Noyori, Tetrahedron Lett., 37, 5141-5144 (1996).

No.47Homochiral and Heterochiral Dimers of the Methylzinc Alkoxide Formed from Dimethylzinc and Enantiomeric 3-exo-(Dimethylamino)isoborneol-Origin of the Distinct Differences in Solution-Phase Behavior and Crystal Structures.

M. Kitamura, M. Yamakawa, H. Oka, S. Suga, and R. Noyori, Chem. Eur. J., 2, 1173-1181 (1996).

No.46Conformational Study on 2-Acyl-1-alkylidene-1,2,3,4-tetrahydroisoquinolines.

M. Kitamura, M. Tsukamoto, H. Takaya, and R. Noyori, Bull. Chem. Soc. Jpn., 69, 1695-1700 (1996).

No.45Effect of the Terminal Branching Structure of Some Liquid-crystalline Biphenyl Carboxylates on the Stability of the Antiferroelectric Phase.

Y. Ouchi, Y. Yoshioka, H. Ishii, K. Seki, M. Kitamura, R. Noyori, Y. Takanishi, and I. Nishiyama, J. Mater. Chem., 5, 2297-2304 (1995).

No.44Stereoselective Organic Synthesis via Dynamic Kinetic Resolution.

R. Noyori, M. Tokunaga, and M. Kitamura, Bull. Chem. Soc. Jpn., 68, 36-56 (1995).

No.43Self and Nonself Recognition of Asymmetric Catalysts. Nonlinear Effects in the Amino Alcohol-Promoted Enantioselective Addition of Dialkylzincs to Aldehydes.

M. Kitamura, S. Suga, M. Niwa, and R. Noyori, J. Am. Chem. Soc., 117, 4832-4842 (1995).

No.42Asymmetric Synthesis of α-Amino β-Hydroxy Phosphonic Acids via BINAP-Ruthenium Catalyzed Hydrogenation.

M. Kitamura, M. Tokunaga, T. Pham, W. D. Lubell, and R. Noyori, Tetrahedron Lett., 32, 5769-5772 (1995).

No.41Asymmetric Hydrogenation of β-Keto Phosphonates: A Practical Way to Fosfomycin.

M. Kitamura, M. Tokunaga, and R. Noyori, J. Am. Chem. Soc., 117, 2931-2932 (1995).

No.40Enantiomer Recognition of Asymmetric Catalysts. Thermodynamic Properties of Homochiral and Heterochiral Dimers of the Methylzinc Alkoxide Formed from Dimethylzinc and Enantiomeric 3-exo-(Dimethylamino)isoborneol.

M. Kitamura, S. Suga, M. Niwa, R. Noyori, Z.-X. Zhai, and H. Suga, J. Phys. Chem., 98, 12776-12781 (1994).

No.39Synthesis of 3-Substituted But-3-enoic Acids via Palladium Catalyzed Cross-Coupling Reaction of 3-Iodobut-3-enoic Acid with Organometallic Reagents.

A. Duchêne, M. Abarbri, J. Parrain, M. Kitamura, and R. Noyori, Synlett, 524–526 (1994).

No.38Asymmetric Hydrogenation of Asymmetric Hydrogenation of Allylic Alcohols Using BINAP-Ruthenium Complexes: (S)-(-)-Citronellol.

H. Takaya, T. Ohta, S. Inoue, M. Tokunaga, M. Kitamura, and R. Noyori, Org. Synth., 72, 74-85 (1994).

No.37General Asymmetric Synthesis of Isoquinoline Alkaloids. Enantioselective Hydrogenation of Enamides Catalyzed by BINAP-Ruthenium(II) Complexes.

M. Kitamura, Yi Hsiao, M. Ohta, M. Tsukamoto, T. Ohta, H. Takaya, R. Noyori, J. Org. Chem., 59, 297-310 (1994).

No.36Mathematical Treatment of Kinetic Resolution of Chirally Labile Substrates.

M. Kitamura, M. Tokunaga, and R. Noyori, Tetrahedron, 49, 1853-1860 (1993).

No.35Quantitative Expression of Dynamic Kinetic Resolution of Chirally Labile Enantiomers: Stereoselective Hydrogenation of 2-Substituted 3-Oxo Carboxylic Esters Catalyzed by BINAP-Ruthenium(II) Complexes.

M. Kitamura, M. Tokunaga, and R. Noyori, J. Am. Chem. Soc., 115, 144-152 (1993).

No.34Asymmetric Hydrogenation of 3-Oxo Carboxylates Using BINAP-Ruthenium Complexes: (R)-(-)-Methyl 3-Hydroxybutanoate.

M. Kitamura, M. Tokunaga, T. Ohkuma, and R. Noyori, Org. Synth., 71, 1-13 (1993).

No.33Practical Synthesis of BINAP-Ruthenium(II) Dicarboxylate Complexes.

M. Kitamura, M. Tokunaga, and R. Noyori, J. Org. Chem., 57, 4053-4054 (1992).

No.32Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication, and Amplification.

R. Noyori and M. Kitamura, Angew. Chem., Int. Ed. Engl., 30, 49-69 (1991); Angew. Chem., 103, 34-55 (1991).

No.31Enantioselective Synthesis of -Amino Acids Based on BINAP-Ruthenium(II) Catalyzed Hydrogenation.

W. D. Lubell, M. Kitamura, and R. Noyori, Tetrahedron: Asymmetry, 2, 543-554 (1991).

No.30Convenient Preparation of BINAP-Ruthenium(II) Complexes Catalyzing Asymmetric Hydrogenation of Functionalized Ketones.

M. Kitamura, M. Tokunaga, T. Ohkuma, and R. Noyori, Tetrahedron Lett., 32, 4163-4166 (1991).

No.29Enantioselective Synthesis of 4-Substituted γ-Lactones.

T. Ohkuma, M. Kitamura, and R. Noyori, Tetrahedron Lett., 31, 5509-5512 (1990).

No.28Dynamic Kinetic Resolution in BINAP-Ruthenium(II) Catalyzed Hydrogenation of 2-Substituted 3-Oxo Carboxylic Esters.

M. Kitamura, T. Ohkuma, M. Tokunaga, and R. Noyori, Tetrahedron:  Asymmetry, 1, 1-4 (1990).

No.27Enantioselective Addition of Diorganozincs to Aldehydes Catalyzed by -Amino Alcohols.

R. Noyori, S. Suga, K. Kawai, S. Okada, M. Kitamura, N. Oguni, M. Hayashi, T. Kaneko, and Y. Matsuda, J. Organomet. Chem., 382, 19-37 (1990).

No.26Stereoselective Synthesis of a Precursor of 1 -Methylcarbapenems.

M. Kitamura, K. Nagai, Yi Hsiao, and R. Noyori, Tetrahedron Lett., 31, 549-552 (1990).

No.25Stereoselective Hydrogenation via Dynamic Kinetic Resolution.

R. Noyori, T. Ikeda, T. Ohkuma, M. Widhalm, M. Kitamura, H. Takaya, S. Akutagawa, N. Sayo, T. Saito, T. Taketomi, and H. Kumobayashi, J. Am. Chem. Soc., 111, 9134-9135 (1989).

No.24Enantioselective Addition of Dialkylzincs to Aldehydes Promoted by Chiral Amino Alcohols. Mechanism and Nonlinear Effect.

M. Kitamura, S. Okada, S. Suga, and R. Noyori, J. Am. Chem. Soc., 111, 4028-4036 (1989).

No.23Organometallics in Prostaglandin Synthesis.

R. Noyori, A. Yanagisawa, H. Koyano, M. Kitamura, M. Nishizawa, and M. Suzuki, Phil. Trans. R. Soc. Lond. A, 326, 579-585 (1988).

No.22Enantioselective Alkylation of Carbonyl Compounds. From Stoichiometric to Catalytic Asymmetric Induction.

R. Noyori, S. Suga, K. Kawai, S. Okada, and M. Kitamura, Pure Appl. Chem., 60, 1597-1606 (1988).

No.21Synthesis of Statine and Its Analogues by Homogeneous Asymmetric Hydrogenation.

T. Nishi, M. Kitamura, T. Ohkuma, and R. Noyori, Tetrahedron Lett., 29, 6327-6330 (1988).

No.20A Practical Asymmetric Synthesis of Carnitine.

M. Kitamura, T. Ohkuma, H. Takaya, and R. Noyori, Tetrahedron Lett., 29, 1555-1556 (1988).

No.19Kinetic Resolution of Racemic Allylic Alcohols by BINAP-Ruthenium(II)-Catalyzed Hydrogenation.

M. Kitamura, I. Kasahara, K. Manabe, R. Noyori, and H. Takaya, J. Org. Chem., 53, 708-710 (1988).

No.18Homogeneous Asymmetric Hydrogenation of Functionalized Ketones.

M. Kitamura, T. Ohkuma, S. Inoue, N. Sayo, H. Kumobayashi, S. Akutagawa, T. Ohta, H. Takaya, and R. Noyori, J. Am. Chem. Soc., 110, 629-631 (1988).

No.17General Asymmetric Synthesis of Benzomorphans and Morphinans via Enantioselective Hydrogenation.

M. Kitamura, Yi Hsiao, R. Noyori, and H. Takaya, Tetrahedron Lett., 28, 4829-4832 (1987).

No.16Kinetic Resolution of 4-Hydroxy-2-cyclopentenone by Rhodium-Catalyzed Asymmetric Isomerization.

M. Kitamura, K. Manabe, R. Noyori, and H. Takaya, Tetrahedron Lett., 28, 4719-4720 (1987).

No.15Asymmetric Hydrogenation of -Keto Carboxylic Esters. A Practical, Purely Chemical Access to -Hydroxy Esters in High Enantiomeric Purity.

R. Noyori, T. Ohkuma, M. Kitamura, H. Takaya, N. Sayo, H. Kumobayashi, and S. Akutagawa, J. Am. Chem. Soc., 109, 5856-5858 (1987).

No.14Asymmetric Hydrogenation of Unsaturated Carboxylic Acids Catalyzed by BINAP-Ruthenium(II) Complexes.

T. Ohta, H. Takaya, M. Kitamura, K. Nagai, and R. Noyori, J. Org. Chem., 52, 3174-3176 (1987).

No.13Asymmetric Synthesis of Isoquinoline Alkaloids by Homogeneous Catalysis.

R. Noyori, M. Ohta, Yi Hsiao, M. Kitamura, T. Ohta, and H. Takaya, J. Am. Chem. Soc., 108, 7117-7119 (1986).

No.12Catalytic Asymmetric Induction. Highly Enantioselective Addition of Dialkylzincs to Aldehydes.

M. Kitamura, S. Suga, K. Kawai, and R. Noyori, J. Am. Chem. Soc., 108, 6071-6072 (1986).

No.11Synthesis of Maytansinoid. A General Approach via Heteroconjugate Addition Strategy and the Total Synthesis of (±)-Maysine and (±)-N-Methylmaysenine.

M. Kitamura, M. Isobe, Y. Ichikawa, and T. Goto, J. Org. Chem., 49, 3517-3527 (1984).

No.10Stereocontrolled Total Synthesis of (-)-Maytansinol.

M. Kitamura, M. Isobe, Y. Ichikawa, and T. Goto, J. Am. Chem. Soc., 106, 3252-3257 (1984).

No.9Stereocontrolled Total Synthesis of (±)-Maytansinol.

M. Isobe, M. Kitamura, and T. Goto, J. Am. Chem. Soc., 104, 4997-4999 (1982).

No.8Total Synthesis of (±)-Maysine and (±)-N-Methylmaysenine.

M. Isobe, M. Kitamura, and T. Goto, Chem. Lett., 1907-1908 (1982).

No.7Selectivity in Epoxidation: Acyclic Diastereo- and Enantio-selection with Peroxide Mediated by Titanium(IV) and with Peracid.

M. Isobe, M. Kitamura, S. Mio, and T. Goto, Tetrahedron Lett., 23, 221-224 (1982).

No.6Synthetic Studies toward Maytansinoids. Preparation of the Optically Active Intermediates from D-Mannose.

M. Isobe, Y. Ichikawa, M. Kitamura, and T. Goto, Chem. Lett., 457-460 (1981).

No.5Synthetic Studies toward Maytansinoids (2). A New Strategy Based on Asymmetric Induction by Heteroconjugate Addition of Methyllithium onto Pyranosyl Hetero-olefins.

M. Isobe, M. Kitamura, and T. Goto, Tetrahedron Lett., 22, 239-242 (1981).

No.4Acyclic Asymmetric Induction with Carbon-carbon Bond Formation.

M. Isobe, M. Kitamura, and T. Goto, Tetrahedron Lett., 21, 4727-4730 (1980).

No.3Heteroconjugate Addition of Lithium Alkyls to Substituted Hetero-olefins Conjugated with Sulfur and Silicon Atoms.

M. Isobe, M. Kitamura, and T. Goto, Chem. Lett., 331-334 (1980).

No.2Complete Asymmetric Induction in Heteroconjugate Addition on an Acyclic System. A New Synthetic Approach Directed toward Ansamacrolide Maytansine.

M. Isobe, M. Kitamura, and T. Goto, Tetrahedron Lett., 3465-3468 (1979).

No.1Substituent Effect on the Ratio of [2,3]-Sigmatropic Rearrangement vs syn-Elimination of Allylic Aryl Sulfoxides.

M. Isobe, H. Iio, M. Kitamura, and T. Goto, Chem. Lett., 541–544 (1978).

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